Dual-phase rare-earth-zirconate high-entropy ceramics with glass-like thermal conductivity

A series of rare earth zirconates (RE₂Zr₂O₇) high-entropy ceramics with single- and dual-phase structure were prepared. Compared with La₂Zr₂O₇ and Yb₂Zr₂O₇, the smaller “rattling” ions (Yb³⁺, Er³⁺, Y³⁺) have been incorporated into pyrochlore lattice in (La_0.2Nd_0.2Y_0.2Er_0.2Yb_0.2)₂Zr₂O₇ (LNYEY) while larger ions (La³⁺, Nd³⁺, Sm³⁺, Eu³⁺) incorporated into fluorite lattice in (La_0.2Nd_0.2Sm_0.2Gd_0.2Yb_0.2)₂Zr₂O₇ (LNSGY). Due to high-entropy lattice distortion and resonant scattering derived from smaller ions Yb³⁺, Er³⁺, and Y³⁺, LNYEY shows a lower glass-like thermal conductivity (1.62-1.59 W m^-1 K^-1, 100-600℃) than LNSGY (1.74-1.75 W m^-1 K^-1, 100-600℃). Moreover, LNYEY and LNSGY exhibit enhanced Vickers’ hardness (LNYEY, H_v = 11.47 ± 0.41 GPa; LNSGY, H_v = 10.96 ± 0.26 GPa) and thermal expansion coefficients (LNYEY, 10.45 × 10^-6 K^-1, 1000℃; LNSGY, 11.02 × 10^-6 K^-1, 1000℃). These results indicate that dual-phase rare-earth-zirconate high-entropy ceramics could be desirable for thermal barrier coatings.     

Apriori算法在手足口病与气象因素关系分析中的应用

探讨长治市手足口病(HFMD)与气象因素的关联关系.利用Apriori关联规则算法挖掘不同气象因素组合引发手足口病的频繁程度.长治市手足口病的周高发、中等发病率与前一周的平均水汽压、气温具有显著相关性.而周低发病率与前一周的气温(最低、平均)、降水量存在显著相关性.长治市手足口病周发病率与气象因素存在一定的关联性,应根据气象条件进行流行风险评估,及时采取相应的防控措施.     

Single-Crystalline TiO2(B) Nanobelts with Unusual Large Exposed {100} Facets and Enhanced Li-Storage Capacity

The {100} facet of single-crystalline TiO₂(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO₂(B) nanobelts from H₂Ti₃O₇ with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO₂ formula with specific capacity up to 335 mAh g⁻¹, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g⁻¹ after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures.     

发酵乳杆菌HCS08-005耐逆性及对体外细胞免疫调节作用的研究

目的 研究发酵乳杆菌(Lactobacillus fermentum) HCS08-005耐逆性及对体外细胞的免疫调节作用。方法 考察发酵乳杆菌HCS08-005的耐酸耐胆盐能力，并应用发酵乳杆菌HCS08-005细胞裂解物，处理小鼠单核巨噬细胞RAW264.7和小鼠脾脏细胞，用酶联免疫吸附测定试剂盒检测各类炎症因子包括肿瘤坏死因子-α (tumor necrosis factor-α，TNF-α)、白细胞介素-2 (inter-leukin-2，IL-2)、白细胞介素-12 (inter-leukin-12，IL-12)、γ干扰素(interferon-γ，IFN-γ)的表达水平。结果 显示发酵乳杆菌HCS08-005有较好的耐逆性，能够耐受酸和胆盐环境到达肠道发挥作用。不同浓度的发酵乳杆菌HCS08-005细胞裂解物对小鼠脾脏细胞和巨噬细胞分泌炎症因子均有极显著影响(P<0.01)，在质量浓度为100 μg/g时，IL-2分泌量为421.49 pg/g，TNF-α分泌量为161.23 pg/g，IFN-γ分泌量为846.14 pg/g，IL-12分泌量为12.88 pg/g，因子水平极显著提高(P<0.01)。结论 在体外细胞试验中，发酵乳杆菌HCS08-005有较好的耐逆性，对体外细胞有免疫调节作用。     

Comprehensive analysis on anomalous phenomenon of ethanol-soluble poly(vinyl butyral) membrane for ethanol recovery via pervaporation

Poly(vinyl butyral) (PVB) is selected as a promising ethanol-permselective membrane based on the solubility parameter theory; however, it exhibits anomalous water perm-selectivity in practical pervaporation (PV) process. Comprehensive analysis based on experimental and theoretical methods were carried out to explore the inherent mechanism of the anomalous performance. Firstly, sum frequency generation vibrational spectra and contact angle were developed to quantify the surface reconstruction of membrane in air and ethanol, which indicated that hydrophilic hydroxyl tended to expose on membrane surface with ethanol thus improving the membrane affinity to water. Meanwhile, swelling behaviors proved more water would accumulate in the ethanol swollen membrane. Furthermore, theoretical analysis in terms of sorption and diffusion process, based on the UNIFAC-FV model and Fujita free-volume theory, confirmed the mechanism of anomalous phenomenon of PVB membrane. The comprehensive investigation was expected to provide insights into the basic separation mechanism of PV process.     

The influence of inner material with different average thermal conductivity on the performance of whole insulation system for liquid hydrogen on orbit storage

At present, several composite insulation systems were proposed that can be used for passive insulation systems, including foam-variable density multilayer insulation (VDMLI), aerogel-VDMLI and hollow glass microspheres (HGMs)-VDMLI. The passive insulation systems with different inner material (IM) showed different performances. However, the relationship between the average thermal conductivity of IM and the insulation performance of the whole system has rarely been investigated. It is of great significance for efficient configuration and matching of the passive insulation system. In this paper, a series of average thermal conductivity of IM were assumed to predict the insulation performance of the whole system at 20 K–300 K and high vacuum. In order to further illustrate the relationship between IM and MLI/VDMLI, the foam was replaced by the HGMs as 5 mm a unit forming a series of HGMs-foam-MLI/VDMLI insulation systems. The performance of the systems was investigated. After the foam was completely replaced by the HGMs, the performance of MLI and VDMLI systems was improved 33% and 13%, respectively. Moreover, each mode of heat transfer including solid conduction, radiation, and gas conduction for foam-MLI/VDMLI and HGMs-MLI/VDMLI insulation systems were calculated and analyzed.     

Object detection based on the multiscale location Enhancement network

For the target detection task,there are two problems in the one-stage network structure of the deep neural network model.First,whether the design of the anchor box hyperparameter is suitable or not will affect the training results of the whole network;second,a large down sampling factor will affect the positioning ability of the target.To solve these problems,this paper proposes a multi-location enhancement network.The structure of the one-stage network model is redesigned,and a better scheme for selecting the super parameters of the anchor frame is proposed.So the efficiency of the first stage network is ensured and the positioning accuracy is better than the previous one.A large number of experiments show that the multi-location enhancement network can achieve a higher positioning accuracy while ensuring real-time performance.The average accuracy of 82.5 is achieved on the public dataset (Pascal VOC 2007).     

三门峡水库汛期排沙效果研究

三门峡水库汛期排沙是解决泥沙淤积问题、控制潼关高程的关键途径。"蓄清排浑"运用以来,非汛期蓄水期库区发生淤积、汛期降低水位运用排泄全年泥沙,基本保持了库区动态冲淤平衡。不同控制水位和入库流量过程存在不同的排沙效果,针对三门峡水库汛期排沙过程的差异,对"蓄清排浑"运用以来汛期排沙特征进行统计,分析了水库敞泄和不同控制水位运用对排沙效果的影响。结果表明,在汛期平水305 m、洪水敞泄的运用条件下,水库排沙具有多来多排的特点,汛期排沙总量与入库含沙量和水量密切相关;完全敞泄时库区冲刷取决于流量大小和敞泄时间,净排沙效率随着水量的增加和敞泄时间的延长而减小,冲刷效率降低;汛期控制运用期,当流量在1000 m~3/s以上时、水位在305～311 m也会产生一定的排沙,排沙效果取决于含沙水流在壅水段的滞留时间和出入库流量之比。研究成果可为三门峡水库运用方式的优化提供依据。